Research Fields and Publications

We have developed a plasmonic nanolaser using colloidal silver nanocubes, which have excellent optical properties. These nanocubes are assembled into a structured pattern using a precise but scalable technique, enabling a unique optical effect called surface lattice resonance (SLR) that can enable lasing feedback. When combined with a laser dye, the system emits a laser beam at 574 nm with a narrow linewidth and low energy threshold, even without perfect nanoparticle arrangement. This approach allows for large-scale production of nanolasers, making them useful for medical diagnostics, optical circuits, and communication technologies. Read more…

This article shows how a transient absorption spectrometer (TAS) can be useful for determining the crystallinity of silver nanoparticles. Silver nanoparticles are interesting because of their plasmonic properties. Localized surface plasmon resonance is known to relax by several processes, such as electron-electron scattering, electron-phonon (e-ph) coupling, and phonon-phonon scattering. Of these processes, the e-ph coupling is the most interesting, as it allows determining where nanoparticles are best used, for example, for photocatalysis (long e-ph coupling) or thermal effects (short e-ph couplin. To determine how the crystalline structure affects the e-ph coupling durations, two types of samples were studied: monocrystalline silver nanocubes and polycrystalline (increasing polycrystallinity with increasing size) silver nanospheres, the sizes of which were in the length range of 30-60 nm. It was found that in monocrystalline nanocubes, the duration of e-ph coupling did not depend on the size of the edge of the cube, while in polycrystalline spheres, the duration of e-ph coupling decreased linearly with increasing diameter. Finally, we have demonstrated that the e-ph coupling decay time constant depends linearly on (Crystallite size / linear dimension of Ag NPs)2 for polycrystalline Ag nanospheres, while monocrystalline Ag nanocubes do not show any clear dependence on this ratio. This fact illustrates that the e-ph coupling time could be used to evaluate crystallinity and crystallite size in plasmonic metal nanoparticles when the size (surface area) of the nanoparticle is known. Read more…

This paper focuses on how the physical and antiviral properties of silver nanoparticle-polymer (AgND-PVB) nanocomposite coatings, formed by photochemical in-situ synthesis, are influenced by their physical and antiviral properties. The nanocomposite coatings were found to be effective in reducing SARS-CoV-2 activity, suggesting that they may be used as long-acting preventive agents against viral infections. A protective coating for a widely used public object, a door handle, was also formed using 3D printing technology. As a result of the work, a long-lasting, durable antiviral AgNPs-PVB nanocomposite coating was successfully developed with AgNPs of different sizes (from 15 to 118 nm) and concentrations (150, 200, 500 and 1000 ppm). Read more…

The combined technique consisting of CF4/O2 plasma nanotexturing of the glass surface and the deposition of the SiOx containing DLC film on the top of the grating scale followed by O2 plasma treatment was designed for the long-lasting protection of the optical grating scales from fogging. XPS analysis of the DLC film before and after O2 plasma treatment shows that even short exposure to O2 plasma produces oxidized silicon on the surface of the DLC film. O2 plasma treatment time of 180 s leads to the increase of the carbon C=C peak (sp2 hybridization) intensity from 15% to 32%, and a decrease of the carbon C-C peak (sp3 hybridization) intensity from 67% to 45%. The wetting angle of the plasma nanotextured and DLC-coated optical grating scale retains superhydrophilic properties and optical transmittance after long-term storage. The proposed technique ensures long-lasting operation of the encoder with the optical grating scale below dew point temperature. Read more…

In this work we analyze how a form of zinc oxide (ZnO) nanomaterials determines their electrochemical properties. Different forms of ZnO were compared: tetrapods, nanoparticles and nanowires. ZnO tetrapods synthesized in our laboratory were found to have better electrochemical properties than commercial ZnO (nanoparticles, nanowires). ZnO tetrapods have the highest active surface area (A = A= 0.095 cm2), and the lowest number of electronic transport skaičiaus (DEp = 61.7 mV), which is very close to the theoretical value. This detailed study of the influence of ZnO nanostructure and form on electrochemical properties, will be useful in the development of future biosensors. Read more…

Herein, photothermal modification of nanocomposite films consisting of hydrated vanadium pentoxide (V2O5·nH2O) nanoribbons wrapped with graphene oxide (GO) flakes was performed via 405 nm direct laser irradiation. The combination of X-ray diffraction, X-ray photoelectron spectroscopy, Raman scattering, transmission electron microscopy, and scanning electron microscopy allowed comprehensive characterization of physical and chemical changes of GO/V2O5·nH2O nanocomposite films upon photothermal modification. The modified nanocomposite films exhibited porous surface morphology (17.27 m2 g–1) consisting of randomly distributed pillarlike protrusions. The photothermal modification process of GO/V2O5·nH2O enhanced the electrical conductivity of nanocomposite from 1.6 to 6.8 S/m. It was also determined that the direct laser irradiation of GO/V2O5·nH2O resulted in considerable decrease of C–O bounds as well as O–H functional groups with an increase of the laser power density. Read more…

This paper describes the results of studies of diamond-like carbon coatings (coatings containing carbon atoms of different spatial configurations – typical for crystalline diamond and graphite) with different concentrations of aluminum nanoparticles (DLC:Al). We investigated two different types of magnetron sputtering deposited DLC coatings: hydrogenated (coatings also contain hydrogen atoms) and non-hydrogenated with different Al atomic concentrations in them. If the studies of the composition of hydrogenated DLC:Al did not show unexpected results – alumina (AlOx) derivatives were formed in these coatings, then in addition to AlOx compounds, aluminum carbide (AlCx) derivatives were formed in non-hydrogenated DLC:Al. It is known that the formation of AlCx is usually very inefficient and requires temperatures above 1000 oC, therefore most often during synthesis, which takes place at much lower temperatures (e.g. room temperature), no AlCx is formed in DLC:Al films. The fact that we were able to obtain AlCx at relatively very low room temperatures is an interesting result, and the better understanding of the synthesis method we used may contribute to the efficient preparation of AlCx coatings in the future. Thanks to their high thermal conductivity, low thermal expansion and high refractive index, these coatings can be widely applied in optoelectronics. The sufficiently simple magnetron-based coating preparation method described in the article may contribute to the wide practical applications of AlCx in the future. Read more…